WHAT IS A THERMODYNAMIC CYCLE?



A thermodynamic cycle is a sequence of processes that begins and ends at the same state. At the conclusion of a cycle all properties have the same values they had at the beginning.

Consequently, over the cycle the system experiences no net change of state. Cycles that are repeated periodically play prominent roles in many areas of application.

For example, steam circulating through an electrical power plant executes a cycle.

At a given state each property has a definite value that can be assigned without knowledge of how the system arrived at that state. Therefore, the change in value of a property as the system is altered from one state to another is determined solely by the two end states and is independent of the particular way the change of state occurred.

That is, the change is independent of the details of the process. Conversely, if the value of a quantity is independent of the process between two states, then that quantity is the change in a property.

This provides a test for determining whether a quantity is a property: A quantity is a property if its change in value between two states is independent of the process.

It follows that if the value of a particular quantity depends on the details of the process, and not solely on the end states, that quantity cannot be a property.

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